Browsing by Author "Brizuela, Marta"
Now showing 1 - 17 of 17
Results Per Page
Sort Options
Item Broadband antireflective coating stack based on mesoporous silica by acid-catalyzed sol-gel method for concentrated photovoltaic application(2018-11) Agustín-Sáenz, Cecilia; Sánchez-García, José Ángel; Machado, Maider; Brizuela, Marta; Zubillaga, Oihana; Tercjak, Agnieszka; Tecnalia Research & Innovation; VALORIZACIÓN DE RESIDUOS; INGENIERÍA DE SUPERFICIES; SISTEMAS FOTOVOLTAICOSSilica multi-layer stacks have been designed with the aim to provide broadband antireflective (AR) properties for glass components in concentrated photovoltaic (CPV) application. Silica porous coatings were grown by combining acid-catalyzed sol-gel route and evaporation induced self-assembly (EISA) method with four types of organic/inorganic systems. Sols were prepared using tetraethylorthosilicate (TEOS) as inorganic precursor assembled with two di-block copolymers, one tri-block copolymer and one cationic surfactant as organic templates. Optical properties were characterized by ellipsometry and spectrophotometry while the material structure was analyzed by environmental ellipsometric porosimetry (EEP) and atomic force microscopy (AFM). The concentration of inorganic and organic phases was optimized and a broadband AR bi-layer stack was obtained providing a 7.2% (under the reference AM1.5 solar spectral irradiance) increase in transmittance over bare glass in the wavelength range 300–2000 nm when coated on both sides.Item Characterization of nanostructured Ti–B–(N) coatings produced by direct current magnetron sputtering(2007-02-26) López-Cartes, C.; Martínez-Martínez, D.; Sánchez-López, J.C.; Fernández, A.; García-Luis, A.; Brizuela, Marta; Onate, J.I.; TECNOLOGÍAS DE HIDRÓGENO; INGENIERÍA DE SUPERFICIES; Tecnalia Research & InnovationA series of Ti–B–(N) coatings prepared by dc magnetron sputtering using TiB2 targets in Ar/N2 gas mixtures has been chemically and structurally characterized by transmission electron microscopy, X-ray diffraction, electron energy-loss spectroscopy, and X-ray photoelectron spectroscopy. The influence of synthesis parameters such as applied heating power and nitrogen flow on the structure and chemical composition of the coatings has been studied. Independently of the experimental conditions employed during the synthesis, hexagonal TiB2 is the main crystalline phase present in the coatings. The use of N2 leads to the formation of an amorphous mixture of BN/TiN phases, as well as a diminution of the TiB2 crystalline phase. The influence of the composition and structure of the coatings on their hardness is also discussed.Item Design of Corrosion Protective and Antistatic Hybrid Sol-Gel Coatings on 6XXX AlMgSi Alloys for Aerospace Application(2020-04-30) Agustín-Sáenz, Cecilia; Santa Coloma, Patricia; Fernández-Carretero, Francisco J.; Brusciotti, Fabiola; Brizuela, Marta; Tecnalia Research & Innovation; VALORIZACIÓN DE RESIDUOS; TECNOLOGÍAS DE HIDRÓGENO; INGENIERÍA DE SUPERFICIESAn inorganic–organic coating based on glycidyl-functionalized silica and zirconia was synthesized by sol-gel technology to protect three types of AlMgSi (6XXX series) alloys against corrosion in aerospace applications. Different parameters such as the solid content, the organic/inorganic ratio of the sols and the deposition conditions were studied with the aim to achieve a tradeoff between the corrosion protection, antistatic performance and low vacuum-induced outgassing. Those parameters directly influence the thickness and the density of the coatings, and therefore the barrier effect against corrosion and the contact electrical resistance, which are affected in opposite ways. To obtain a low contact electrical resistance, silver nanowires (NW) with a high aspect ratio were loaded in the sol-gel matrix with the aim to create a conductive path through the hybrid coating with a low concentration of NWs. The coatings were adapted for AA6063, AA6061 and AA6082, and they all showed an outstanding anti-corrosion performance in different artificial weathering tests, whereas electrochemical impedance spectroscopy permitted the identification of the most critical parameters affecting water uptake. An antistatic performance was demonstrated by the low contact electrical resistance of the coated AA6061 and AA6063 alloys, although the incorporation of NWs showed a detrimental effect on the corrosion protection compared with the unloaded coatingItem Electro-tribological properties of diamond like carbon coatings(2019-06-07) Braceras, Iñigo; Ibáñez, Iñigo; Dominguez-Meister, Santiago; Velasco, Xabier; Brizuela, Marta; Garmendia, Iñaki; Tecnalia Research & Innovation; INGENIERÍA DE SUPERFICIESDiamond like carbon (DLC) coatings typically present good self-lubricating tribological properties that could be of interest in sliding dielectric contacts in multiple electrical applications. In this work electro-tribological studies have been performed on several DLC coatings against aluminum in different humidity conditions, in which the coefficients of friction (CoFs) and electrical contact resistance (ECR) were continuously monitored. Results show that CoF and ECR data can be linked to the properties of the coatings (thickness, finishing, microstructure, residual stresses, and wettability) and the degradation modes of their tribological and electrical properties. Therefore, electro-tribological data can provide valuable information about the performance of dielectric coatings, the reasons behind it, and assist in the development of the coatings. ECR also shows potential for on-line monitoring of coated parts in operation.Item Improved osseointegration in ion implantation-treated dental implants(2002-09) Braceras, I.; Alava, J.I.; Onate, J.I.; Brizuela, Marta; García-Luis, A.; Garagorri, N.; Viviente, J.L.; de Maeztu, M.A.; Oate, J. I.; INGENIERÍA DE SUPERFICIES; Tecnalia Research & Innovation; TECNOLOGÍAS DE HIDRÓGENO; TECNOLOGÍA DE MEMBRANAS E INTENSIFICACIÓN DE PROCESOSImplants for knee, hip and dental part replacement are becoming increasingly used in surgery. Unfortunately, their use is sometimes accompanied by failure due to infection, inflammation, integration problems with the surrounding tissues or bone, and implant failure due to mishandling. Surface treatment, such as ion implantation, has been identified as a good candidate to modify the surface properties of the implant to significantly improve its osseointegration. This work reports on the ion implantation of light ions in commercial Ti6Al4V dental implants and subsequent osseointegration tests. Various light ions were implanted (C, N, CO, Ne) with energy ranging from 45 to 100 keV and doses up to 5×10e17 ions/cm2. Both ion-implanted and control dental implants were inserted in the tibial plateau of adult rabbits, the epiphysis and diaphysis of the tibia for the evaluation of their degree of osseointegration. After 3 months the implants were extracted and several histological sections were prepared from whole bones for evaluation of their osseointegration in the tibia. In addition, the surface of the implant, and the interface between the bone and the implant were examined by scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS) techniques. Some ion implantation treatments did not significantly change the performance of the dental implants relative to the untreated implants, while tests showed that the ion implantation of CO remarkably improved the osseointegration properties, i.e. the percentage of bone and implant in contact.Item Magnetron sputtering of Cr(Al)N coatings: Mechanical and tribological study: Mechanical and tribological study(2005-10-01) Brizuela, Marta; García-Luis, A.; Braceras, I.; Onate, J.I.; Sánchez-López, J.C.; Martínez-Martínez, D.; López-Cortés, C.; Fernández, A.; López-Cartes, C.; INGENIERÍA DE SUPERFICIES; TECNOLOGÍAS DE HIDRÓGENO; Tecnalia Research & InnovationCrN coatings produced by magnetron sputtering are routinely deposited on tools and components for machining and forming applications. This paper reports on the effect of additions of aluminium (<15 at.%) on the mechanical and tribological properties of CrN coatings. Aluminium has been incorporated into CrN by co-sputtering of chromium and aluminium in a mixture of argon and nitrogen. Mechanical properties have been evaluated by ultramicroindentation techniques and scratch testing, while tribological tests have been carried out against ball bearing steel and titanium alloy balls by the pin-on-disc method. The thermal stability and oxidation resistance of the coatings have also been examined. A significant increase in hardness, reaching values up to 35 GPa, has been achieved for the CrAlN coatings when compared to CrN coatings. The improvement in tribological properties has also been remarkable, with a decrease in friction coefficient against bearing steel and also a non-adhesive wear mechanism against titanium alloy balls. In addition, the CrAlN coatings exhibited higher thermal stability than pure CrN coatings.Item Mechanical behavior and oxidation resistance of Cr (Al) N coatings(2005-06-21) Sánchez-López, J.C.; Martínez-Martínez, D.; López-Cartes, C.; Fernández, A.; Brizuela, Marta; García-Luis, A.; Onate, J.I.; INGENIERÍA DE SUPERFICIES; TECNOLOGÍAS DE HIDRÓGENO; Tecnalia Research & InnovationNanocrystalline chromium nitride and ternary chromium aluminium nitride thin films were deposited by reactive magnetron sputtering of Cr and Al targets in argon/nitrogen atmosphere varying the sputtering power and gas composition. The coatings were characterized in terms of crystal phase, chemical composition, microstructure, and mechanical properties by x-ray diffraction, x-ray photoelectron spectroscopy, including x-ray-induced Auger electron spectroscopy, transmission electron microscopy, selected-area electron diffraction, electron energy-loss spectroscopy, cross-sectional scanning electron microscopy, and ultramicrohardness tester. The incorporation of Al in the composition of the films produces an increase in the mechanical properties (hardness and reduced Young's modulus) and an increased thermal resistance against oxidation in comparison to the pure CrN composition. The hardness behavior was attributed mainly to a reduction of the CrN crystallite size according to a Hall-Petch relationship. The oxidation resistance was evaluated after annealing both types of coatings in air up to 800 degrees C. The oxygen content and the crystallite size appear almost unaltered in the CrAIN in contrast to the pure CrN films where the oxidation and grain growth is very noticeable at 800 degrees C. This improvement in thermal stability in air is explained by the formation of a nanocomposite structure of small CrN crystals embedded in an amorphous aluminum oxide or oxinitride matrix that prevents the CrN phase from crystal growth and further oxidationItem Mechanical properties of nanocrystalline Ti–B–(N) coatings produced by DC magnetron sputtering(2005-10-01) García-Luis, A.; Brizuela, Marta; Onate, J.I.; Sánchez-López, J.C.; Martínez-Martínez, D.; López-Cartes, C.; Fernández, A.; TECNOLOGÍAS DE HIDRÓGENO; INGENIERÍA DE SUPERFICIES; Tecnalia Research & InnovationTi–B–(N) coatings have been deposited by DC magnetron sputtering using TiB2 targets in Ar/N2 gas mixtures. The influence of bias voltage and nitrogen flow on the mechanical and tribological properties of these coatings has been studied. Mechanical properties have been evaluated by ultra-microindentation techniques and scratch testing; tribology tests have been performed in a pin-on-disc apparatus with controlled humidity conditions. Microstructural characterization by X-ray diffraction (XRD) and Transmission Electron Microscopy (TEM) demonstrates the nanocrystalline structure of Ti–B–(N) coatings and allows the interpretation of their mechanical behaviour. Hardness values up to 58 GPa have been achieved, depending on deposition conditions. Increasing the bias voltage on the substrates improves the hardness of coatings, while the addition of nitrogen significantly decreases these values. Coating adhesion obtained on highspeed steel is very good in most cases, reaching values higher than 60 N of critical load. Tribotests performed on these coatings against a Steel contact (wear conditions: 0.98 N load, 10 cm/s, 50% RH, 10 mm bearing steel ball diameter) have yielded very low wear rates but friction coefficients in the range of 0.6–1.0.Item MoSx lubricant coatings produced by PVD technologies(2007-03-01) Onate, J.I.; Brizuela, Marta; Viviente, J.L.; García-Luis, A.; Braceras, I.; Gonzalez, D.; Garmendia, Iñaki; Tecnalia Research & Innovation; INGENIERÍA DE SUPERFICIES; TECNOLOGÍA DE MEMBRANAS E INTENSIFICACIÓN DE PROCESOS; TECNOLOGÍAS DE HIDRÓGENOAmong the different options for solid lubrication, MoS2 is probably the most attractive due to its extremely low friction levels. Recent developments in magnetron sputtering physical vapour deposition (PVD) technology have allowed the development of MoS2 composite thin films with more compact structures, low friction behaviour and enhanced wear resistance, reducing degradation by humidity. The present work provides an overview of recent developments in dry lubrication with MoS2 films deposited by modern sputtering PVD and how these MoS2 films alloyed with Ti or WC can outperform conventional unalloyed films not only under vacuum but also under atmospheric high humidity conditions. MoSx–WC composite films outperform MoSx–Ti films, showing endurance at 0·75 GPa as high as 1·2 million wear cycles, also significantly higher than the values obtained from unalloyed, conventional MoS2 thin solid films. The films also exhibit a steady state friction coefficient from 0·02 to 0·04. In addition, these films also show resistance to humid environment when tested under atmospheric conditions.Item Nitriding of titanium by hollow cathode assisted active screen plasma and its electro-tribological properties(2021-04-15) Domínguez-Meister, Santiago; Ibáñez, Iñigo; Dianova, Anastasia; Brizuela, Marta; Braceras, Iñigo; Tecnalia Research & Innovation; INGENIERÍA DE SUPERFICIESTitanium presents good corrosion resistance, a high strength-to-weight ratio, but poor tribological properties. However, these can be enhanced by nitriding processes. Hollow cathode assisted active screen plasma has proved to be an effective and fast nitriding technique. In this work, the effect of process parameters (hollow cathode induced temperature and plasma intensity, electrical bias…) on the resulting surface microstructure (XRD, SEM/EDS), finishing and hardness of titanium (TiGr4) have been studied. Additionally, the electro-tribological properties have been evaluated on a ball on cylinder reciprocating configuration. The results show that hollow cathode assisted active screen plasma nitriding of titanium can produce titanium nitride surfaces with thicknesses far exceeding those typical in PVD coatings. Moreover, higher plasma processing intensities can generate same layer thicknesses at lower temperatures, minimizing the deleterious effect on grain size growth. Finally, monitoring of the electrical contact resistance can provide valuable information concerning the evolution of the status of the surfaces.Item Plasma nitriding of the inner surface of stainless steel tubes(2018-12-15) Braceras, Iñigo; Ibáñez, Iñigo; Dominguez-Meister, Santiago; Sánchez-García, Jose Angel; Brizuela, Marta; Larrañaga, Aitor; Garmendia, Iñaki; Tecnalia Research & Innovation; INGENIERÍA DE SUPERFICIESStainless steels, especially the austenitic grades, present a good corrosion resistance but poor mechanical properties. Nitriding can increase the surface hardness but typically at the expense of corrosion resistance. Besides, nitriding of inner surfaces is not straight forward, as control of the plasma there is challenging. This work has focused on the development of active screen plasma nitriding processes of inner geometries of the widely used AISI 316L austenitic stainless steel, with preservation of the corrosion resistance. The structure and composition of the nitrided surfaces were studied and corrosion resistance of the inner surfaces assessed. As a result of the study, a relation has been established between plasma treatment parameters, geometrical features and the corrosion resistance. Additionally, electro-tribological studies have been performed. It has been observed that wear resistance improved and that ECR (Electrical Contact Resistance) is a good indicator of the wear phenomena occurring along the test and potentially could be a useful and simple monitoring tool of the status of the surface and assist in defining safe and dependable operational lives. As part of the study, an equivalent electric circuit is proposed. In conclusion, treatment conditions for AISI316L inner tube surfaces have been defined, with corrosion resistance preservation and improved tribological performance, while ECR monitoring has been found insightful and informative of the evolution of the later.Item Solid lubricant behavior of MoS2 and WSe2-based nanocomposite coatings(2017-01-01) Domínguez-Meister, Santiago; Rojas, Teresa Cristina; Brizuela, Marta; Sánchez-López, Juan Carlos; Tecnalia Research & Innovation; INGENIERÍA DE SUPERFICIESTribological coatings made of MoS2 and WSe2 phases and their corresponding combinations with tungsten carbide (WC) were prepared by non-reactive magnetron sputtering of individual targets of similar composition. A comparative tribological analysis of these multiphase coatings was done in both ambient air (30–40% relative humidity, RH) and dry nitrogen (RH<7%) environments using the same tribometer and testing conditions. A nanostructural study using advanced transmission electron microscopy of the initial coatings and examination of the counterfaces after the friction test using different analytical tools helped to elucidate what governs the tribological behavior for each type of environment. This allowed conclusions to be made about the influence of the coating microstructure and composition on the tribological response. The best performance obtained with a WSex film (specific wear rate of 2 × 10−8 mm3 N–1m–1 and a friction coefficient of 0.03–0.05) was compared with that of the well-established MoS2 lubricant material.Item Tailored synthesis of TiC/a-C nanocomposite tribological coatings(2005-10-25) Martínez-Martínez, D.; López-Cartes, C.; Justo, A.; Fernández, A.; Sánchez-López, J.C.; García-Luis, A.; Brizuela, Marta; Onate, J.I.; TECNOLOGÍAS DE HIDRÓGENO; INGENIERÍA DE SUPERFICIES; Tecnalia Research & InnovationComposite coatings made of nanocrystalline TiC (nc-TiC) particles and amorphous carbon (a-C) have been prepared in a double magnetron sputtering system using graphite and titanium targets under Ar bombardment. Chemical composition and microstructure of coatings were studied by transmission electron microscopy (TEM), electron energy loss spectroscopy (EELS), and x-ray diffraction (XRD) for a set of samples prepared varying the ratio and intensity of power applied to each magnetron. Changes in coatings microstructure, from a quasipolycrystalline TiC to a nanocomposite formed by nanocrystals of TiC embedded in an amorphous matrix of carbon (nc-TiC/a-C), are observed depending on the synthesis conditions. Tribological and mechanical properties of coatings were tested using a pin-on-disk tribometer and an ultramicrohardness indenter, respectively. Coatings with moderate hardness (7-27 GPa), low friction (0.1-0.2), and low wear rates (k similar to 10(-7) mm(3)/N m) were obtained. A percentage between 15% and 30% of TiC is found as an optimum value to get a good compromise between good mechanical and tribological properties. Finally, a mapping of the mechanical and tribological properties of the nc-TiC/a-C system is presented for the synthesis conditions employedItem Thermal Control of Tribolab, a materials experiment in the International Space Station(Servicio de Publicaciones de la Universidad de Navarra, 2012-05) Garmendia, Iñaki; Anglada, Eva; Vallejo, Haritz; Brizuela, Marta; Insausti, NagoreTribolab is a materials tribology experiment that was flown on the International Space Station (ISS) from February 2008 to September 2009. The main objective of the experiment was the study of the behaviour of new solid lubricants (alloyed MoS2 with WC) under real space conditions. The thermal control of the instrument (techniques needed to ensure that the temperature range of the experiment components are adequate in all the mission possible scenarios) was designed, assembled, integrated and tested by a team of engineers of Inasmet-Tecnalia and INTA. The design concept employed, mainly passive thermal control with some active components, is explained in detail. The computational models devised for the design, as well as the different mission scenarios are also explained. The verification and on earth qualification tests are described and the difficulties encountered during the project for the thermal subsystem are also explained. Finally, the real thermal behaviour of the experiment when on space is described, with some post-flight information.Item TiN-Ag as an antimicrobial and wear resistant coating(2021-12) Braceras, Iñigo; Brizuela, Marta; Álvarez, Noelia; Martínez Van Geeteruyen, Miguel; Azkona, Ibon; INGENIERÍA DE SUPERFICIES; BiomaterialesNosocomial infections are a major clinical concern, posing great risks for patients and rising costs for health services providers. This work aims at developing a hard, wear resistant coating, whose antimicrobial properties shall prevent the transmission of infections. TiN coatings deposited by Physical Vapour Deposition, PVD, with different Ag contents have been studied, especially in relation to the hardness and adhesion, their microstructure and morphology. The antimicrobial activity of the surfaces has been assessed against Staphylococcus epidermidis at different time frames, one of the most troublesome source of infections in trauma and orthopaedic surgeries. The electro-tribology properties of different silver contest have been studied. Finally, the coatings have been deposited on surgical acetabular reamers and wear resistance tests have been carried out against synthetic composite bone (simulating cortical and cancellous bone). Results have shown a good coating adhesion on stainless steel (both quantitatively in the scratch tests and qualitatively in the tests against synthetic composite bone), while the hardness decreased with higher Ag percentages. Furthermore, coatings exhibited antimicrobial activity against S.epidermidis, limited silver release, a remarkable wear resistance (vs. uncoated surgical acetabular reamers), while the electrical contact resistance provided valuable information about the evolution of friction and the status of the coating. Therefore TiN-Ag coatings present promising features for reducing the risk of infections, monitoring and extending cutting edge life and quality, and thus limiting damage to living tissues, e.g. necrosis.Item TriboLAB: Características de un Tribómetro para un Experimento de Tribología Espacial en la ISS(Tekniker, 2007-06) Garmendia, Iñaki; Anglada, Eva; Landaberea, Aitor; Vallejo, Haritz; Brizuela, Marta; Martinez, Cesar; Fernandez, RamónTriboLAB es un instrumento para la experimentación tribológica en órbita que, junto con otros dispositivos europeos, forma parte de la plataforma EuTEF, la cual se instalará en la Estación Espacial Internacional en Octubre de 2007. Se presentan las características de este tribómetro en lo referente a aspectos estructurales, montaje, inspección, verificación, operacionales, electrónicos, térmicos y de software.Item Wear reduction effect on ultra-high-molecular-weight polyethylene by application of hard coatings and ion implantation on cobalt chromium alloy, as measured in a knee wear simulation machine(2001-07) Onate, J.I.; Comin, M.; Braceras, I.; García-Luis, A.; Viviente, J.L.; Brizuela, Marta; Garagorri, N.; Peris, J.L.; Alava, J.I.; Oate, J. I.; Garcia, A.; Tecnalia Research & Innovation; INGENIERÍA DE SUPERFICIES; TECNOLOGÍA DE MEMBRANAS E INTENSIFICACIÓN DE PROCESOSThe most important factor affecting performance and longevity of hip joint and knee implants is the wear rate of the ultra-high-molecular-weight polyethylene (UHMWPE) component. UHMWPE wear debris has been linked to complications including tissue inflammation, bone loss (osteolysis) and implant loosening. Reduction of debris has been addressed by investigating new polyethylene formulations, manufacturing and finishing processes, including surface treatments and coatings both on plastic and metallic components. There have been many studies on the effect of surface treatments and hard coatings on cobalt chromium and titanium alloys for prosthetic applications. However, most of them have used laboratory tribo-testers without much correlation to articulating movements in human joints. In this work, hard coatings (TiN and DLC) and surface treatments (nitrogen ion implantation) have been investigated as potential candidates to reduce wear of UHMWPE, when applied on the counter face cobalt chromium alloy. Also the effect of applying nitrogen ion implantation on the UHMWPE surface itself has been investigated. To evaluate wear performance a special knee wear simulator has been used with a combined rolling-sliding movement that corresponds to the most unfavourable situation in the knee. As testing materials, conventional coated and uncoated Co–Cr as well as Al2O3 femoral heads were used against UHMWPE plates to obtain comparative data. Testing was carried out at 50 MPa using distilled water at 37±2°C as a lubricant. Wear measurements on UHMWPE were made following ASTM F732 standard by weight loss measurements and also by laser profilometry. The results, up to 5 million wear cycles that represent approximately 3 years of implant life, clearly have demonstrated the beneficial effects of diamond-like carbon (DLC) and ion implantation (both on Co–Cr and UHMWPE) in reducing wear of UHMWPE. Similar values were also obtained for Al2O3 ceramic material. A wear reduction up to approximately five times was obtained by the former materials, in comparison with the uncoated control specimen. However, the ion plated TiN coating increased significantly wear on the UHMWPE. Transference of UHMWPE to the ball was very evident with the uncoated control and TiN coated Co–Cr, as observed by SEM, but with DLC and the ceramic material this occurred to a much lesser extent. Some micro-delamination at the worn surface of the UHMWPE was observed when wearing against uncoated Co–Cr, but was not clear in the rest options. Ion implantation and DLC can thus be two good candidate treatments to reduce wear of UHMWPE in cobalt chromium knee and hip joint implants in substitution of a more expensive ceramic material. This DLC has passed all biocompatible tests in accordance with FDA regulations and ISO 10993 standards for implantable devices. An example of a uniformly DLC coated femoral head and knee implant is shown.