Broadband antireflective coating stack based on mesoporous silica by acid-catalyzed sol-gel method for concentrated photovoltaic application
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2018-11
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Abstract
Silica multi-layer stacks have been designed with the aim to provide broadband antireflective (AR) properties for glass components in concentrated photovoltaic (CPV) application. Silica porous coatings were grown by combining acid-catalyzed sol-gel route and evaporation induced self-assembly (EISA) method with four types of organic/inorganic systems. Sols were prepared using tetraethylorthosilicate (TEOS) as inorganic precursor assembled with two di-block copolymers, one tri-block copolymer and one cationic surfactant as organic templates. Optical properties were characterized by ellipsometry and spectrophotometry while the material structure was analyzed by environmental ellipsometric porosimetry (EEP) and atomic force microscopy (AFM). The concentration of inorganic and organic phases was optimized and a broadband AR bi-layer stack was obtained providing a 7.2% (under the reference AM1.5 solar spectral irradiance) increase in transmittance over bare glass in the wavelength range 300–2000 nm when coated on both sides.
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Publisher Copyright: © 2018 Elsevier B.V.
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Antireflection , Broadband , Silica , Porous coating , Acid-catalyzed , Sol-gel , Antireflection , Broadband , Silica , Porous coating , Acid-catalyzed , Sol-gel , Electronic, Optical and Magnetic Materials , Renewable Energy, Sustainability and the Environment , Surfaces, Coatings and Films , SDG 7 - Affordable and Clean Energy , Project ID , info:eu-repo/grantAgreement/EC/H2020/640873/EU/Concentrating Photovoltaic modules using advanced technologies and cells for highest efficiencies/CPVMATCH , info:eu-repo/grantAgreement/EC/H2020/640873/EU/Concentrating Photovoltaic modules using advanced technologies and cells for highest efficiencies/CPVMATCH , Funding Info , This work was supported by the Basque Government for EMAITEK 2017 program as well as the ELKARTEK projects FRONTIERS-2 (Contract no. KK2016-00093 ) and FRONTIERS-3 (Contract no. KK2017-00096 ) This work has received funding from the European Union's Horizon 2020 Research and Innovation Programme within the project CPVMatch under Grant agreement no. 640873 . The authors are solely responsible for the content of this work and it only reflects the author's view. The authors thank ICV-CSIC, Yolanda Castro and Alicia Durán for ellipsometry and EEP measurements. , This work was supported by the Basque Government for EMAITEK 2017 program as well as the ELKARTEK projects FRONTIERS-2 (Contract no. KK2016-00093 ) and FRONTIERS-3 (Contract no. KK2017-00096 ) This work has received funding from the European Union's Horizon 2020 Research and Innovation Programme within the project CPVMatch under Grant agreement no. 640873 . The authors are solely responsible for the content of this work and it only reflects the author's view. The authors thank ICV-CSIC, Yolanda Castro and Alicia Durán for ellipsometry and EEP measurements.
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Agustín-Sáenz , C , Sánchez-García , J Á , Machado , M , Brizuela , M , Zubillaga , O & Tercjak , A 2018 , ' Broadband antireflective coating stack based on mesoporous silica by acid-catalyzed sol-gel method for concentrated photovoltaic application ' , Solar Energy Materials and Solar Cells , vol. 186 , pp. 154-164 . https://doi.org/10.1016/j.solmat.2018.06.040