Browsing by Keyword "Chemistry (miscellaneous)"
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Item Central lessons from the historical analysis of 24 reinforced-concrete structures in northern Spain(2016-07-01) Marcos, Ignacio; San-José, José Tomás; Garmendia, Leire; Santamaría, Amaia; Manso, Juan Manuel; Tecnalia Research & InnovationSince the late-nineteenth century, the use of reinforced-concrete as a structural material has proliferated and is now commonplace in the modern built environment. Some of the structures from that century are even considered cultural heritage. In the early stages of its technical development, concrete was seen as practically immutable over time; however, prolonged exposure to environmental agents has revealed its very significant problems of weakening strength and durability. A total of 24 aging reinforced-concrete structures in the Basque Country (northern Spain) and their behavior over time are analyzed in this paper. Reference is made to pathological reports, categorized for the purposes of this study, which characterize their concrete and steel components. This contribution greatly enhances our knowledge of each structure for future studies and for the improvement of their conservation strategies.Item Effect of the Metal Transfer Mode on the Symmetry of Bead Geometry in WAAM Aluminum(2021-07-10) Veiga, Fernando; Suárez, Alfredo; Aldalur, Eider; Bhujangrao, Trunal; Tecnalia Research & Innovation; FABRIC_INTELThe symmetrical nature in the case of wall fabrication by wire arc additive manufacturing (WAAM) has been observed in the literature, but it has not been studied as a source of knowledge. This paper focuses on the comparative study of three drop transfer methods employing Gas Metal Arc Welding (GMAW) technology, one of the most reported for the manufacture of aluminum alloys. The transfer modes studied are the well-known pulsed GMAW, cold arc, and the newer pulsed AC. The novelty of the last transfer mode is the reversal of the polarity during the preparation phase of the substance for droplet deposition. This study compares the symmetry of zero beads to determine the best parameters and transfer modes for wire arc additive manufacturing of 5 series aluminum. The pulsed transfer modes show values of 0.6 for symmetry ratio, which makes them more interesting strategies than cold arc with a symmetry ratio of 0.5. Furthermore, the methodology proposed in this study can be extrapolated to other materials manufactured with this technology.Item Fluidized Bed Membrane Reactors for Ultra Pure H2 Production - A Step forward towards Commercialization(2016-03-19) Helmi, Arash; Fernandez, Ekain; Melendez, Jon; Pacheco Tanaka, David A.; Gallucci, Fausto; van Sint Annaland, Martin; TECNOLOGÍAS DE HIDRÓGENO; Tecnalia Research & Innovation; TECNOLOGÍA DE MEMBRANAS E INTENSIFICACIÓN DE PROCESOSIn this research the performance of a fluidized bed membrane reactor for high temperature water gas shift and its long term stability was investigated to provide a proof-of-concept of the new system at lab scale. A demonstration unit with a capacity of 1 Nm3/h of ultra-pure H2 was designed, built and operated over 900 h of continuous work. Firstly, the performance of the membranes were investigated at different inlet gas compositions and at different temperatures and H2 partial pressure differences. The membranes showed very high H2 fluxes (3.89E 6 mol m 2 Pa 1 s 1 at 400 C and 1 atm pressure difference) with a H2/N2 ideal perm-selectivity (up to 21,000 when integrating five membranes in the module) beyond the DOE 2015 targets. Monitoring the performance of the membranes and the reactor confirmed a very stable performance of the unit for continuous high temperature water gas shift under bubbling fluidization conditions. Several experiments were carried out at different temperatures, pressures and various inlet compositions to determine the optimum operating window for the reactor. The obtained results showed high hydrogen recovery factors, and very low CO concentrations at the permeate side (in average <10 ppm), so that the produced hydrogen can be directly fed to a low temperature PEM fuel cell.Item Morphology and N2 Permeance of Sputtered Pd-Ag Ultra-Thin Film Membranes(2016-02-10) Fernandez, Ekain; Sanchez-Garcia, Jose Angel; Viviente, J.L.; van Sint Annaland, Martin; Gallucci, Fausto; Pacheco Tanaka, David A.; Tecnalia Research & Innovation; TECNOLOGÍAS DE HIDRÓGENO; TECNOLOGÍA DE MEMBRANAS E INTENSIFICACIÓN DE PROCESOSThe influence of the temperature during the growth of Pd-Ag films by PVD magnetron sputtering onto polished silicon wafers was studied in order to avoid the effect of the support roughness on the layer growth. The surfaces of the Pd-Ag membrane films were analyzed by atomic force microscopy (AFM), and the results indicate an increase of the grain size from 120 to 250–270 nm and film surface roughness from 4–5 to 10–12 nm when increasing the temperature from around 360–510 K. After selecting the conditions for obtaining the smallest grain size onto silicon wafer, thin Pd-Ag (0.5–2-µm thick) films were deposited onto different types of porous supports to study the influence of the porous support, layer thickness and target power on the selective layer microstructure and membrane properties. The Pd-Ag layers deposited onto ZrO2 3-nm top layer supports (smallest pore size among all tested) present high N2 permeance in the order of 10−6 mol•m−2•s−1•Pa−1 at room temperature.Item Pore flow-through catalytic membrane reactor for steam methane reforming: characterization and performance(2022-07-12) Angulo, M.; Agirre, I.; Arratibel, A.; Llosa Tanco, M. A.; Pacheco Tanaka, D. A.; Barrio, V. L.; TECNOLOGÍA DE MEMBRANAS E INTENSIFICACIÓN DE PROCESOSA series of pore flow-through catalytic nonselective membrane reactors (PTCMRs) were studied for steam methane reforming (SMR) in the 500 to 900 °C temperature range under 10 barg pressure and a steam-to-carbon ratio of 5. The reactants flow through the pores of the membrane where they react on contact with the Pd nanoparticles. Various reactor configurations were prepared and tested with porous α-Al2O3-based ceramic tubes with one or more γ-Al2O3/YSZ layers on the external surface. The palladium content and dispersion affect the catalytic activity of the reactors and the results show that the efficiency of the reactions depends on the number of γ-Al2O3/YSZ layers.Item Recent Advances in Pd-Based Membranes for Membrane Reactors(2017-01-01) Arratibel Plazaola, Alba; Pacheco Tanaka, David A.; Van Sint Annaland, Martin; Gallucci, Fausto; Tecnalia Research & Innovation; TECNOLOGÍA DE MEMBRANAS E INTENSIFICACIÓN DE PROCESOSPalladium-based membranes for hydrogen separation have been studied by several research groups during the last 40 years. Much effort has been dedicated to improving the hydrogen flux of these membranes employing different alloys, supports, deposition/production techniques, etc. High flux and cheap membranes, yet stable at different operating conditions are required for their exploitation at industrial scale. The integration of membranes in multifunctional reactors (membrane reactors) poses additional demands on the membranes as interactions at different levels between the catalyst and the membrane surface can occur. Particularly, when employing the membranes in fluidized bed reactors, the selective layer should be resistant to or protected against erosion. In this review we will also describe a novel kind of membranes, the pore-filled type membranes prepared by Pacheco Tanaka and coworkers that represent a possible solution to integrate thin selective membranes into membrane reactors while protecting the selective layer. This work is focused on recent advances on metallic supports, materials used as an intermetallic diffusion layer when metallic supports are used and the most recent advances on Pd-based composite membranes. Particular attention is paid to improvements on sulfur resistance of Pd based membranes, resistance to hydrogen embrittlement and stability at high temperature.Item Supercritical hydrothermal flow synthesis of xonotlite nanofibers(2018-06-01) Díez-García, Marta; Gaitero, J.J.; Santos, J.I.; Dolado, Jorge S.; Aymonier, Cyril; Tecnalia Research & Innovation; ECOEFICIENCIA DE PRODUCTOS DE CONSTRUCCIÓNThis article reports a satisfactory and innovative method for the synthesis of xonotlite using a flow reactor and supercritical water. This study widens the variety of inorganic nanofibers produced in record breaking times by means of continuous reactors working under supercritical water conditions. In particular, the synthesis time of xonotlite, which takes normally more than 5 h, was reduced to only 20s by carrying out the reaction at 400 °C and 23.5 MPa. Resulting product was studied by several characterization techniques: x-ray diffraction, transmission electron microscopy, 29Si and 1H nuclear magnetic resonance and infrared spectroscopy. Furthermore, obtained product consisted of highly pure and crystalline flat nanofibers of 1–10 μm long with a length to diameter ratio of the order of 100. Also, the typical deviation from the ideal structure observed by nuclear magnetic resonance and the presence of Si-OH were explained in terms of surface defects. This work reinforces the interests of using supercritical conditions for the fast synthesis of crystalline nano-calcium silicates which, due to the number of potential industrial applications and the scalability of the technology, might represent technological breakthrough.Item Three-Dimensional Finite Element Modelling of Sheet Metal Forming for the Manufacture of Pipe Components: Symmetry Considerations: Symmetry Considerations(2022-01-25) Bhujangrao, Trunal; Veiga, Fernando; Penalva, Mariluz; Costas, Adriana; Ruiz, Cristina; Tecnalia Research & Innovation; FABRIC_INTELThe manufacture of parts by metal forming is a widespread technique in sectors such as oil and gas and automotives. It is therefore important to make a research effort to know the correct set of parameters that allow the manufacture of correct parts. This paper presents a process analysis by means of the finite element model. The use case presented in this paper is that of a 3-m diameter pipe component with a thickness of 22 mm. In this type of application, poor selection of process conditions can result in parts that are out of tolerance, both in dimensions and shape. A 3D finite element model is made, and the symmetry of the tube section generated in 2D is analysed. As a novelty, an analysis of the process correction as a function of the symmetrical deformation of the material in this case in the form of a pipe is carried out. The results show a correct fitting of the model and give guidelines for manufacturing.