Browsing by Keyword "Capacitive deionization"
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Item Bacterial-cellulose-derived carbonaceous electrode materials for water desalination via capacitive method: The crucial role of defect sites: The crucial role of defect sites(2020-10-15) Belaustegui, Yolanda; Pantò, Fabiola; Urbina, Leire; Corcuera, Maria Angeles; Eceiza, Arantxa; Palella, Alessandra; Triolo, Claudia; Santangelo, Saveria; VALORIZACIÓN DE RESIDUOSElectrosorptive desalination is a very simple and appealing approach to satisfy the increasing demand for drinking water. The large-scale application of this technology calls for the development of easy-to-produce, cheap and highly performing electrode materials and for the identification and tailoring of their most influential properties, as well. Here, biosynthesised bacterial cellulose is used as a carbon precursor for the production of three-dimensional nanostructures endowed with hierarchically porous architecture and different density and type of intrinsic and hetero-atom induced lattice defects. The produced materials exhibit unprecedented desalination capacities for carbon-based electrodes. At an initial concentration of 585 mg L−1 (10 mmol L−1), they are able to remove from 55 to 79 mg g−1 of salt; as the initial concentration rises to 11.7 g L−1 (200 mmol L−1), their salt adsorption capacity reaches values ranging between 1.03 and 1.35 g g−1. The results of the thorough material characterisation by complementary techniques evidence that the relative amount of oxygenated surface functional species enhancing the electrode wettability play a crucial role at lower NaCl concentrations, whereas the availability of active non-sp2 defect sites for adsorption is mainly influential at higher salt concentrations.Item Evaluation of the Specific Capacitance of High-Entropy Oxide-Based Electrode Materials in View of Their Use for Water Desalination via Capacitive Method(Multidisciplinary Digital Publishing Institute (MDPI), 2023-01-04) Triolo, Claudia; Santangelo, Saveria; Petrovičovà, Beatrix; Musolino, Maria Grazia; Rincón, Inés; Atxirika, Ainhoa; Gil, Silvia; Belaustegui, YolandaWater pollution and scarcity are serious concerns for the growing world population. To meet the ever-pressing demand of fresh water, a variety of desalting techniques of seawater have been developed. Due to its environmental friendliness, high efficiency, easy regeneration of the electrodes, ambient operating pressure, and low operating potential suitable for the use in remote areas, the capacitive deionization (CDI) method is one of the most sustainable among them. This work focuses on the preparation of high-entropy oxides (HEOs) and carbon/HEO composites and the evaluation of their specific capacitance in view of their possible use as CDI electrode materials. CrMnFeCoNi-HEO, having spinel structure (sHEO), is obtained in the form of nanoparticles (NPs) and nanofibers (NFs) by the sol–gel method and electrospinning, respectively. Composite NFs with embedded sHEO NPs or MgCoNiCuZn-HEO NPs with rock-salt structure (rHEO) are also produced. In the 5–100 mV s−1 scan rate range, the specific capacitance improves in the order C/rHEO NFs (8–32 F g−1) ≅ sHEO NPs (9–32 F g−1) < sHEO NFs (8–43 F g−1) < C/sHEO NFs (12–66 F g−1). The highest capacitance is obtained when the beneficial contributions of the carbon matrix and smaller-sized HEO NPs are synergistically coupled.