RT Journal Article T1 Growth of nano-textured graphene coatings across highly porous stainless steel supports towards corrosion resistant coatings A1 Dumée, Ludovic F. A1 He, Li A1 Wang, Ziyu A1 Sheath, Phillip A1 Xiong, Jianyu A1 Feng, Chunfang A1 Tan, Mike Yongjun A1 She, Fenghua A1 Duke, Mikel A1 Gray, Stephen A1 Pacheco, Alfredo A1 Hodgson, Peter A1 Majumder, Mainak A1 Kong, Lingxue AB In this paper, we demonstrated for the first time the growth of 3D networks of graphene nano-flakes across porous stainless steel substrates of micron sized metal fibres, and its anti-corrosion properties. The controlled formation of graphene-grade coatings in the form of single sheets to complex and homogeneously distributed 2-4 μm long nano-pillars is demonstrated by Scanning Electron Microscopy. The morphology and stability of these structures are shown to be particularly related to the temperature and feed gas flow rate during the growth. The number of layers across the graphene materials was calculated from the Raman spectra and is shown to range between 3 and more than 15 depending on the growth conditions and to be particularly related to the time and flow rate of the experiment. The presence of the graphene was shown to massively enhance the specific surface area of the material and to contribute to the increased corrosion resistance and electrical conductivity of the material without compromising the properties or structure of the native stainless steel materials. This new approach opens up a new route to the facile fabrication of advanced surface coatings with potential applications in developing new thermal exchangers, separation and bio-compatible materials. SN 0008-6223 YR 2015 FD 2015-02-01 LA eng NO Dumée , L F , He , L , Wang , Z , Sheath , P , Xiong , J , Feng , C , Tan , M Y , She , F , Duke , M , Gray , S , Pacheco , A , Hodgson , P , Majumder , M & Kong , L 2015 , ' Growth of nano-textured graphene coatings across highly porous stainless steel supports towards corrosion resistant coatings ' , Carbon , vol. 87 , no. C , pp. 395-408 . https://doi.org/10.1016/j.carbon.2015.02.042 NO Publisher Copyright: © 2015 Elsevier Ltd. All rights reserved. NO The authors acknowledge the Cooperative Research Network (CRN2012/2) initiative of the Australian Department of Industry and Dr. DUMEE’s Alfred Deakin Fellowship for funding and supporting this work. They also thank Dr. Mark Nave and Dr. Andrew Sullivan for fruitful discussion for SEM imaging, Dr. Pimm Vongsvivut for assistance with Raman spectroscopy (Waurn Ponds, Victoria – Australia) and Dr. Rob Jones (Latrobe University, Victoria – Australia) for assistance with XPS data analysis. DS TECNALIA Publications RD 4 jul 2024