RT Journal Article T1 Growth of carbon layers on Ti-6Al-4V alloy by very high dose carbon implantation A1 García, A. A1 Viviente, J. L. A1 Alonso, F. A1 Loinaz, A. A1 Oñate, J. I. AB Ion implantation is a useful technique to tailor the surface properties of Ti-6Al-4V alloys. In particular, very high dose C+ implantation (in the range of 1018 ions cm-2) offers the possibility of forming carbon layers without a sharp interface with the substrate material. In this study, ion implantation treatments have been performed on Ti-6Al-4V with C+ doses up to 4 × 1018 ions cm-2. XPS analyses have been carried out to evaluate the chemical states after ion implantation. A change in C 1s binding energies has been observed depending on the carbon concentration in the implanted layer. At relatively low or medium concentrations (about 41 at.% C) mainly carbidic bonds were present, but when the concentration increased up to 88 at.%, the binding peak shifted to values that correspond to C-C bonds. Dynamic microindentation techniques, used to evaluate the hardness of the implanted material, have shown a significant change in relative hardness as a function of C+ dose, owing to the formation of a carbon layer in the titanium alloy surface. A two-fold increase in the hardness ratio and elastic recovery values is observed for the highest implanted dose. SN 0257-8972 YR 1997 FD 1997-12 LK https://hdl.handle.net/11556/3117 UL https://hdl.handle.net/11556/3117 LA eng NO García , A , Viviente , J L , Alonso , F , Loinaz , A & Oñate , J I 1997 , ' Growth of carbon layers on Ti-6Al-4V alloy by very high dose carbon implantation ' , Surface and Coatings Technology , vol. 97 , no. 1-3 , pp. 499-503 . https://doi.org/10.1016/S0257-8972(97)00131-X NO This work has been carried out with the financial support of the Spanish Comisión Interministerial de Ciencia y Tecnologı́a (CICYT). DS TECNALIA Publications RD 30 jul 2024