RT Journal Article
T1 Preparation and characterization of metallic supported thin Pd–Ag membranes for hydrogen separation
A1 Fernandez, Ekain
A1 Medrano, Jose Antonio
A1 Melendez, Jon
A1 Parco, Maria
A1 Viviente, Jose Luis
A1 van Sint Annaland, Martin
A1 Gallucci, Fausto
A1 Pacheco Tanaka, D. A.
AB This paper reports the preparation and characterization of thin-film (4–5 μm thick) Pd–Ag metallic supported membranes for high temperature applications. Various thin film membranes have been prepared by depositing a ceramic interdiffusion barrier layer prior to the simultaneous Pd–Ag electroless plating deposition. Two deposition techniques for ceramic layers (made of zirconia and alumina) have been evaluated: Atmospheric Plasma Spraying and dip coating of a powder suspension. Initially, the prepared ceramic layers have been characterized for nitrogen permeation at room temperature and surface roughness for the selection of the appropriate type of ceramic layer. The most promising membranes have been tested at 400–600 °C for single gas permeation (H2 and N2), and have shown extremely high H2/N2 permselectivities (>200,000).
SN 1385-8947
YR 2016
FD 2016-12-01
LA eng
NO Fernandez , E , Medrano , J A , Melendez , J , Parco , M , Viviente , J L , van Sint Annaland , M , Gallucci , F & Pacheco Tanaka , D A 2016 , ' Preparation and characterization of metallic supported thin Pd–Ag membranes for hydrogen separation ' , Chemical Engineering Journal , vol. 305 , pp. 182-190 . https://doi.org/10.1016/j.cej.2015.09.119
NO Publisher Copyright: © 2015 Elsevier B.V.
NO The presented work is funded within ReforCELL project as part of the European Union’s Seventh Framework Programme (FP7/2007–2013) under Grant agreements n° 278997 (for the Fuel Cells and Hydrogen Joint Technology Initiative). Note: “The present publication reflects only the author’s views and the FCH JU and the Union are not liable for any use that may be made of the information contained therein”. Also NWO/STW is acknowledged for the financial support through the VIDI project number 12365.
DS TECNALIA Publications
RD 1 jul 2024