Metal-organic framework based mixed matrix membranes: a solution for highly efficient CO2 capture?: A solution for highly efficient CO2 capture?
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2015-04-21
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Abstract
The field of metal-organic framework based mixed matrix membranes (M(4)s) is critically reviewed, with special emphasis on their application in CO2 capture during energy generation. After introducing the most relevant parameters affecting membrane performance, we define targets in terms of selectivity and productivity based on existing literature on process design for pre- and post-combustion CO2 capture. Subsequently, the state of the art in M(4)s is reviewed against these targets. Because final application of these membranes will only be possible if thin separation layers can be produced, the latest advances in the manufacture of M-4 hollow fibers are discussed. Finally, the recent efforts in understanding the separation performance of these complex composite materials and future research directions are outlined.
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Publisher Copyright: © 2015 The Royal Society of Chemistry.
Keywords
hollow-fiber membranes , hansen solubility parameters , gas separation performance , carbn-dioxide capture , zeolitic imidazolate frameworks , nano-composite membranes , IGCC power-plants , of-the-art , nanocomposite membranes , hydrogen separation , hollow-fiber membranes , hansen solubility parameters , gas separation performance , carbn-dioxide capture , zeolitic imidazolate frameworks , nano-composite membranes , IGCC power-plants , of-the-art , nanocomposite membranes , hydrogen separation , General Chemistry , SDG 13 - Climate Action , Project ID , info:eu-repo/grantAgreement/EC/FP7/608490/EU/Energy efficient MOF-based Mixed Matrix Membranes for CO2 Capture/M4CO2 , info:eu-repo/grantAgreement/EC/FP7/608490/EU/Energy efficient MOF-based Mixed Matrix Membranes for CO2 Capture/M4CO2 , Funding Info , European Commission FP7 608490_x000D_ ERC 335746 , European Commission FP7 608490_x000D_ ERC 335746
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Seoane , B , Coronas , J , Gascon , I , Etxeberria-Benavides , M , Karvan , O , Caro , J , Kapteijn , F , Gascon , J & Caro , J 2015 , ' Metal-organic framework based mixed matrix membranes: a solution for highly efficient CO2 capture? A solution for highly efficient CO 2 capture? ' , unknown , vol. unknown , no. 8 , pp. 2421-2454 . https://doi.org/10.1039/c4cs00437j