Rheological characterization of tetraglycidyl 4,4′-diaminodiphenylmethane/m-phenylene diamine systems

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1992-03
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An epoxy resin/hardener system, TGDDM/m-PDA, has been studied. A series of isothermal rheological runs provided information about the kinetics of curing over a temperature range. Both important parameters of the curing reaction (resin/hardener stoichiometry and temperature) were varied and their influence on viscosity was investigated. The dependence of viscosity on temperature was described by using Williams-Landel-Ferry treatment and the gelation process was studied using viscosity profiles during curing cycles.
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Imaz , J J , Markaide , N , Jurado , M J , Corcuera , M A & Mondragon , I 1992 , ' Rheological characterization of tetraglycidyl 4,4′-diaminodiphenylmethane/m-phenylene diamine systems ' , European Polymer Journal , vol. 28 , no. 3 , pp. 299-303 . https://doi.org/10.1016/0014-3057(92)90193-6