Preparation and characterization of metallic supported thin Pd–Ag membranes for hydrogen separation

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dc.contributor.authorFernandez, Ekain
dc.contributor.authorMedrano, Jose Antonio
dc.contributor.authorMelendez, Jon
dc.contributor.authorParco, Maria
dc.contributor.authorViviente, Jose Luis
dc.contributor.authorvan Sint Annaland, Martin
dc.contributor.authorGallucci, Fausto
dc.contributor.authorPacheco Tanaka, D. A.
dc.contributor.institutionTECNOLOGÍAS DE HIDRÓGENO
dc.contributor.institutionTecnalia Research & Innovation
dc.contributor.institutionEXTREMAT
dc.contributor.institutionTECNOLOGÍA DE MEMBRANAS E INTENSIFICACIÓN DE PROCESOS
dc.date.issued2016-12-01
dc.descriptionPublisher Copyright: © 2015 Elsevier B.V.
dc.description.abstractThis paper reports the preparation and characterization of thin-film (4–5 μm thick) Pd–Ag metallic supported membranes for high temperature applications. Various thin film membranes have been prepared by depositing a ceramic interdiffusion barrier layer prior to the simultaneous Pd–Ag electroless plating deposition. Two deposition techniques for ceramic layers (made of zirconia and alumina) have been evaluated: Atmospheric Plasma Spraying and dip coating of a powder suspension. Initially, the prepared ceramic layers have been characterized for nitrogen permeation at room temperature and surface roughness for the selection of the appropriate type of ceramic layer. The most promising membranes have been tested at 400–600 °C for single gas permeation (H2 and N2), and have shown extremely high H2/N2 permselectivities (>200,000).en
dc.description.sponsorshipThe presented work is funded within ReforCELL project as part of the European Union’s Seventh Framework Programme (FP7/2007–2013) under Grant agreements n° 278997 (for the Fuel Cells and Hydrogen Joint Technology Initiative). Note: “The present publication reflects only the author’s views and the FCH JU and the Union are not liable for any use that may be made of the information contained therein”. Also NWO/STW is acknowledged for the financial support through the VIDI project number 12365.
dc.description.statusPeer reviewed
dc.format.extent9
dc.identifier.citationFernandez , E , Medrano , J A , Melendez , J , Parco , M , Viviente , J L , van Sint Annaland , M , Gallucci , F & Pacheco Tanaka , D A 2016 , ' Preparation and characterization of metallic supported thin Pd–Ag membranes for hydrogen separation ' , Chemical Engineering Journal , vol. 305 , pp. 182-190 . https://doi.org/10.1016/j.cej.2015.09.119
dc.identifier.doi10.1016/j.cej.2015.09.119
dc.identifier.issn1385-8947
dc.identifier.otherresearchoutputwizard: 11556/201
dc.identifier.urlhttp://www.scopus.com/inward/record.url?scp=84991106827&partnerID=8YFLogxK
dc.language.isoeng
dc.relation.ispartofChemical Engineering Journal
dc.relation.projectIDSeventh Framework Programme, FP7, 12365-278997
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subject.keywordsAlumina
dc.subject.keywordsH separation
dc.subject.keywordsInterdiffusion barrier layer
dc.subject.keywordsMetallic support
dc.subject.keywordsPalladium membrane preparation
dc.subject.keywordsZirconia
dc.subject.keywordsGeneral Chemistry
dc.subject.keywordsGeneral Chemical Engineering
dc.subject.keywordsIndustrial and Manufacturing Engineering
dc.subject.keywordsEnvironmental Chemistry
dc.titlePreparation and characterization of metallic supported thin Pd–Ag membranes for hydrogen separationen
dc.typejournal article
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