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Item Microstructural Evolution as a Function of Increasing Aluminum Content in Novel Lightweight Cast Irons(2021-10-18) Obregon, Alejandro; Sanchez, Jon Mikel; Eguizabal, David; Garcia, Jose Carlos; Arruebarrena, Gurutze; Hurtado, Iñaki; Quintana, Ion; Rodriguez, Patxi; PROMETAL; CIRMETALIn the context of the development of new lightweight materials, Al-alloyed cast irons have a great potential for reducing the weight of the different part of the vehicles in the transport industry. The correlation of the amount of Al and its effect in the microstructure of cast irons is not completely well established as it is affected by many factors such as chemical composition, cooling rate, etc. In this work, four novel lightweight cast irons were developed with different amounts of Al (from 0 wt. % to 15 wt. %). The alloys were manufactured by an easily scalable and affordable gravity casting process in an induction furnace, and casted in a resin-bonded sand mold. The microstructural evolution as a function of increasing Al content by different microstructural characterization techniques was studied. The hardness of the cast irons was measured by the Vickers indentation test and correlated with the previously characterized microstructures. In general, the microstructural evolution shows that the perlite content decrease with the increment of wt. % of Al. The opposite occurs with the ferrite content. In the case of graphite, a slight increment occurs with 2 wt. % of Al, but a great decrease occurs until 15 wt. % of Al. The addition of Al promotes the stabilization of ferrite in the studied alloys. The hardness obtained varied from 235 HV and 363 HV in function of the Al content. The addition of Al increases the hardness of the studied cast irons, but not gradually. The alloy with the highest hardness is the alloy containing 7 wt. % Al, which is correlated with the formation of kappa-carbides and finer perlite.Item Microstructure and Phase Formation of Novel Al80Mg5Sn5Zn5X5 Light-Weight Complex Concentrated Aluminum Alloys(2021-12-01) Sanchez, Jon Mikel; Pascual, Alejandro; Vicario, Iban; Albizuri, Joseba; Guraya, Teresa; Galarraga, Haize; CIRMETAL; PROMETALIn this work, three novel complex concentrated aluminum alloys were developed. To investigate the unexplored region of the multicomponent phase diagrams, thermo-physical parameters and the CALPHAD method were used to understand the phase formation of the Al80Mg5Sn5Zn5Ni5 , Al80Mg5Sn5Zn5Mn5 , and Al80Mg5Sn5Zn5Ti5 alloys. The ingots of the alloys were manufactured by a gravity permanent mold casting process, avoiding the use of expensive, dangerous, or scarce alloying elements. The microstructural evolution as a function of the variable element (Ni, Mn, or Ti) was studied by means of different microstructural characterization techniques. The hardness and compressive strength of the as-cast alloys at room temperature were studied and correlated with the previously characterized microstructures. All the alloys showed multiphase microstructures with major α-Al dendritic matrix reinforced with secondary phases. In terms of mechanical properties, the developed alloys exhibited a high compression yield strength up to 420 MPa, high compression fracture strength up to 563 MPa, and elongation greater than 12%.