Browsing by Author "Galarza, N."
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Item Exposure assessment to engineered nanoparticles handled in industrial workplaces: The case of alloying nano-TiO2 in new steel formulations: The case of alloying nano-TiO2 in new steel formulations(2016-12-01) Vaquero-Moralejo, Celina; Gutierrez-Cañas, C.; Galarza, N.; López de Ipiña, J.M.; López de Ipiña, J. L.; Tecnalia Research & Innovation; PRINTEX; SMART_MONThis experimental study addresses the occupational exposure assessment to nano-TiO2 (AEROXIDE ® TiO2 P 25, EVONIK GmbH) along the processing steps of ingot steelmaking at three sites, whose characteristics range from conditioned room to multi-source industrial environments (MSIS). In Site A, which is a MSIS of multiproduct flexible production, the alloying tablets are manufactured through compression of bulk nano-powder at room temperature. Tablets are then assembled in Site B, which is a lab room equipped with local exhaust ventilation (LEV). The alloying of steel takes place in Site C, which is a full-scale casting hall where substantial amounts of material per batch (3000 kg steel/batch) are processed in open-face molds and severe working conditions prevail. A comprehensive experimental strategy based on simultaneous measurements using direct reading instruments (DRI) and time integrated filter-based sampling has been set up. The main goal of this unusual campaign at an industrial site was to determine the suitability of the various options within the decision frame of the current methodological approaches, mainly chemical- and site-dependent. In Site A the DRI were of limited applicability for the quantification of exposure, because of a high-variability of the background and a characteristic low but unstable counting in the coarse size range where agglomerates of nano-TiO2 are present. In Site B, under controlled environmental conditions no interferences were relevant. Therefore, real-time devices showed no change in the total particle concentration suggesting that tasks performed did not result in any detectable release of the nano-powder. Readings in the size range>0.3 µm showed low-signals, in the order of the device accuracy, that could not be linked to any potential release. However, the mass concentration of TiO2, as obtained by the off-line analysis of personal breathing zone (PBZ) samples, spans from 0.021 to 0.296 mg/m3 in both Sites, which seems to be due to big agglomerates observed by scanning electron microcopy (SEM). In Site C (steel foundry) the on-line instruments could not be used due to access restrictions and severe working conditions. Therefore, only personal sampling approach was used, including the comparative study with and without nanomaterial, which indicates no additional or TiO2 specific workers exposure. This work highlights how, in this particular case, occupational exposure to engineered nanoparticles (ENP) is better assessed through off-line analysis of personal filter samples. The DRI, however, are of unquestionable applicability as real-time monitors to quantify engineering controls efficiency and, thus, for risk management activities and decision making. The need for a scientific consensus in performing such an exposure assessment in industrial contexts is stressed.Item IN-SERVICE INSPECTION OF AERONAUTICS PARTS PRODUCED BY ADDITIVE LAYER MANUFACTURING (ALM) - in the framework of Bionic Aircraft project (GA nº 690689)(AEND, 2019) Galarza, N.; Rubio, B.; Bereziartua, A.; Lozano, I.; Gascon, Jaime; Atxaga, G.; Perez, J.; Rubio, J.Bionic Aircraft is a project founded under the H2020 Framework Program and it is a result of a need to reduce emissions due to the impact of the growth of the aviation industry. The introduction of Additive Laser Manufacturing (ALM) to produce some metal aircraft parts is considered as an opportunity to address this issue. This technology allows to produce ultra-lightweight and highly complex parts (so-called “bionic parts”). One of the actions to consider in the project is the development of new NDT strategies to inspect, in-service, parts produced by ALM made of Al-based alloys. This need arises because, ALM processes for these alloys are at low maturity level (TRL2) and hence, no proven and certified NDT methods are yet developed. Moreover, in-service inspection of aeronautic bionic parts involves challenges like the uncertainty of the inner inspection of a layered material, the lack of accessibility (the part is attached to the aircraft fuselage), and the expected defects under in-service conditions, something still under study. The objective of this work is to assess the inspection, in-service, of this kind of parts, by selecting and customizing the most suitable NDT methods, according to the type and maximum tolerable damage sizes estimated by a fatigue life prediction evaluation.Item Occupational exposure to nano-TiO2 in the life cycle steps of new depollutant mortars used in construction(2015-05-26) Vaquero-Moralejo, Celina; Galarza, N.; López de Ipiña, J.M.; Gutierrez-Cañas, C.; Múgica, I.; Aragón, G.; Jaen, M.; Pina, R.; Larraza, I.; Esteban-Cubillo, A.; Thompson, D.; Pui, D.Y.H.; Gelarza, N.; De Ipiña, J. L.López; Tecnalia Research & Innovation; PRINTEX; SMART_MONThe present work is focused on the measurement of workers exposure to nano-TiO2 in the life cycle steps of depollutant mortars. It has been done in the framework of the SCAFFOLD project, which aims at the management of potential risks arising from the use of manufactured nanomaterials in construction. Main findings can be summarized as follows: (1) The occupational exposure to nano- TiO2 is below 0.3 mg/m3 for all measured scenarios. The highest concentrations were measured during the cleaning task (in the nano- TiO2 manufacturing process) and during the application (spraying) of depollutant coatings on a wall. (2) It was found a high release of particles above the background in several tasks as expected due to the nature of the activities performed. The maximum concentration was measured during drilling and during adding powder materials (mean total particle concentration up to 5.591E+04 particles/cm3 and 5.69E+04 particles/cm3). However, considering data on total particle concentration released, no striking differences have been observed when tasks have been performed using conventional materials in the sector (control) and when using materials doped with nano-objects.Item On Limitations of the Ultrasonic Characterization of Pieces Manufactured with Highly Attenuating Materials(2015) Ramos, A.; Moreno, E.; Rubio, B.; Calas, H.; Galarza, N.; Rubio, J.; Diez, L.; Castellanos, L.; Gómez, T.; SMART_MON; INDUSTRY_THINGSSome technical aspects of two Spanish cooperation projects, funded by DPI and Innpacto Programs of the R&D National Plan, are discussed. The objective is to analyze the common belief about than the ultrasonic testing in MHz range is not a tool utilizable to detect internal flaws in highly attenuating pieces made of coarse-grained steel. In fact high-strength steels, used in some safe industrial infrastructures of energy & transport sectors, are difficult to be inspected using the conventional “state of the art” in ultrasonic technology, due to their internal microstructures are very attenuating and coarse-grained. It is studied if this inspection difficulty could be overcome by finding intense interrogating pulses and advanced signal processing of the acquired echoes. A possible solution would depend on drastically improving signal-to-noise-ratios, by applying new advances on: ultrasonic transduction, HV electronics for intense pulsed driving of the testing probes, and an “ad-hoc” digital processing or focusing of the received noisy signals, in function of each material to be inspected. To attain this challenging aim on robust steel pieces would open the possibility of obtaining improvements in inspecting critical industrial components made of highly attenuating & dispersive materials, as new composites in aeronautic and motorway bridges, or new metallic alloys in nuclear area, where additional testing limitations often appear.Item Phase Velocity Method for Guided Wave Measurements in Composite Plates(2015) Moreno, E.; Galarza, N.; Rubio, B.; Otero, J.A.; SMART_MONCarbon Fiber Reinforced Polymer is a well-recognized material for aeronautic applications. Its plane structure has been widely used where anisotropic characteristics should be evaluated with flaw detection. A phase velocity method of ultrasonic guided waves based on a pitch-catch configuration is presented for this purpose. Both shear vertical (SV) and shear horizontal (SH) have been studied. For SV (Lamb waves) the measurements were done at different frequencies in order to evaluate the geometrical dispersion and elastic constants. The results for SV are discussed with an orthotropic elastic model. Finally experiments with lamination flaws are presented.Item Polyfire project- an example of an industrial research project promoting safe industrial production of fire-resistant nanocomposites(2011) Vaquero-Moralejo, Celina; López de Ipiña, J.M.; Galarza, N.; Hargreaves, B.; Weager, B.; Breen, C.; Tecnalia Research & InnovationNew developments based on nanotechnology have to guarantee safe products and processes to be accepted by society. The Polyfire project will develop and scale-up techniques for processing halogen-free, fire-retardant nanocomposite materials and coatings based on unsaturated polyester resins and organoclays. The project includes a work package that will assess the Health and Environmental impacts derived from the manipulation of nanoparticles. This work package includes the following tasks: (1) Identification of Health and Environment Impacts derived from the processes, (2) Experimentation to study specific Nanoparticle Emissions, (3) Development of a Risk Management Methodology for the process, and (4) A Comparison of the Health and Environmental Impact of New and Existing Materials. To date, potential exposure scenarios to nanomaterials have been identified through the development of a Preliminary Hazard Analysis (PHA) of the new production processes. In the next step, these scenarios will be studied and simulated to evaluate potential emissions of nanomaterials. Polyfire is a collaborative European project, funded by the European Commission 7th Framework Programme (Grant Agreement No 229220). It features 11 partners from 5 countries (5 SMEs, 3 research institutes, 2 large companies, 1 association) and runs for three years (1st September 2009 – 31st August 2012). This project is an example of an industrial research development which aims to introduce to the market new products promoting the safe use of nanomaterials.