Show simple item record

dc.contributor.authorArratibel Plazaola, Alba
dc.contributor.authorPacheco Tanaka, David A.
dc.contributor.authorVan Sint Annaland, Martin
dc.contributor.authorGallucci, Fausto
dc.date.accessioned2017-11-10T10:59:43Z
dc.date.available2017-11-10T10:59:43Z
dc.date.issued2017-01
dc.identifier.citationAlba Arratibel Plazaola, David Pacheco Tanaka, Martin Van Sint Annaland, and Fausto Gallucci. “Recent Advances in Pd-Based Membranes for Membrane Reactors.” Molecules 22, no. 1 (January 1, 2017): 51. doi:10.3390/molecules22010051.en
dc.identifier.issn1420-3049en
dc.identifier.urihttp://hdl.handle.net/11556/454
dc.description.abstractPalladium-based membranes for hydrogen separation have been studied by several research groups during the last 40 years. Much effort has been dedicated to improving the hydrogen flux of these membranes employing different alloys, supports, deposition/production techniques, etc. High flux and cheap membranes, yet stable at different operating conditions are required for their exploitation at industrial scale. The integration of membranes in multifunctional reactors (membrane reactors) poses additional demands on the membranes as interactions at different levels between the catalyst and the membrane surface can occur. Particularly, when employing the membranes in fluidized bed reactors, the selective layer should be resistant to or protected against erosion. In this review we will also describe a novel kind of membranes, the pore-filled type membranes prepared by Pacheco Tanaka and coworkers that represent a possible solution to integrate thin selective membranes into membrane reactors while protecting the selective layer. This work is focused on recent advances on metallic supports, materials used as an intermetallic diffusion layer when metallic supports are used and the most recent advances on Pd-based composite membranes. Particular attention is paid to improvements on sulfur resistance of Pd based membranes, resistance to hydrogen embrittlement and stability at high temperature.en
dc.description.sponsorshipThe presented work is funded within Reforcell (grant agreement No. 278997) and FERRET (grant agreement No. 621181) projects as part of European Union's Seventh Framework Programme (FP7/2007-2013) for the Fuel Cells and Hydrogen Joint Technology Initiative.en
dc.language.isoengen
dc.publisherMDPI AG, ST ALBAN-ANLAGE 66, CH-4052 BASEL, SWITZERLANDen
dc.rightsAttribution 4.0 International*
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/*
dc.titleRecent Advances in Pd-Based Membranes for Membrane Reactorsen
dc.typearticleen
dc.identifier.doi10.3390/molecules22010051en
dc.isiYesen
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/FP7/278997/EU/Advanced Multi-Fuel Reformer for Fuel Cell CHP Systems/REFORCELLen
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/FP7/621181/EU/A Flexible natural gas membrane Reformer for m-CHP applications/FERRETen
dc.rights.accessRightsopenAccessen
dc.subject.keywordsMembranesen
dc.subject.keywordsMembrane reactoren
dc.subject.keywordsPore-filleden
dc.subject.keywordsPalladium membranesen
dc.subject.keywordsInorganic membranesen
dc.issue.number1en
dc.journal.titleMoleculesen
dc.volume.number22en


Files in this item

Thumbnail

    Show simple item record

    Attribution 4.0 InternationalExcept where otherwise noted, this item's license is described as Attribution 4.0 International