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dc.contributor.authorCacho-Bailo, Fernando
dc.contributor.authorCatalan-Aguirre, Silvia
dc.contributor.authorEtxeberria-Benavides, Miren
dc.contributor.authorKarvan, Oguz
dc.contributor.authorSebastian, Victor
dc.contributor.authorTellez, Carlos
dc.contributor.authorCoronas, Joaquin
dc.date.accessioned2016-06-06T14:49:05Z
dc.date.available2016-06-06T14:49:05Z
dc.date.issued2015-02-15
dc.identifier.citationJournal of Membrane Science Vol. 476 (2015), pp. 277-285en
dc.identifier.issn0376-7388en
dc.identifier.urihttp://hdl.handle.net/11556/239
dc.description.abstractPolymeric hollow fiber membranes represent a high degree of process intensification closer to scaling up. Metal organic framework ZIF-7 and ZIF-8 continuous membranes were synthesized on the inner surface of a 520 mu m outer diameter polysulfone hollow fiber using microlluidics. This provided a constant reactant concentration along the membrane for growing homogeneous, continuous and thin layers of ZIF-7 (2.4 mu m) and ZIF-8 (3.6 mu m) with good adherence. The high quality of the membranes and the zeolite-like sodalite porous structure of both MOFs with pore apertures of 0.30-0.34 nm allowed operation at high temperature (150 degrees C) and pressure (4 bar). High separation factors in CO2 and H-2 containing mixtures were achieved.en
dc.description.sponsorshipSpanish MINECO MAT2010-15870 MAT2013-40556-R, Aragon Government (DGA), ESF, DGA fellowshipen
dc.language.isoengen
dc.publisherELSEVIER SCIENCE BVen
dc.titleMetal-organic framework membranes on the inner-side of a polymeric hollow fiber by microfluidic synthesisen
dc.typearticleen
dc.identifier.doi10.1016/j.memsci.2014.11.016en
dc.isiYesen
dc.rights.accessRightsembargoedAccessen
dc.subject.keywordsMetal-organic framework (MOF)en
dc.subject.keywordsMicrofluidicsen
dc.subject.keywordsGas separationen
dc.subject.keywordsHydrogen separationen
dc.subject.keywordsZIF-8 membraneen
dc.subject.keywordsHollow-fiber membranesen


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