High-Performance Carbon Electrodes Modified with Polyaniline for Stable and Selective Anion Separation
Date
2022-06Keywords
Capacitive Deionization
Ion Selectivity
Polyaniline
Conducting Polymer
Electrode Stability
Abstract
Capacitive deionization (CDI) is a technology used for water desalination and ion recovery based on the use of capacitive electrodes. Typically, the porous carbon electrodes used for CDI display limited ion storage capacity and selectivity due to the mechanism of ion storage in the electric double layer, but impressive improvements have been achieved using alternative, redox-based electrode materials, including conducting polymers like polyaniline (PAni). PAni is capable of capturing anions based on redox chemistry, but it degrades at anodic potentials typically used in CDI. In this work, we employed a multi-channel membrane CDI cell to map the stability window of a porous carbon electrode modified with PAni by controlling the anodic potential. We demonstrated for the first time that applying a potential as low as + 0.35 V (vs. Ag/AgCl) yields a stable and high chloride removal capacity (65 mgCl/gAnode) with charge and coulombic efficiencies close to 100% for CDI. Furthermore, this is ...
Type
journal article