%0 Journal Article 
%A Seoane, Beatriz
%A Coronas, Joaquin
%A Gascon, Ignacio
%A Etxeberria-Benavides, Miren
%A Karvan, Oguz
%A Caro, Juergen
%A Kapteijn, Freek
%A Gascon, Jorge
%T Metal-organic framework based mixed matrix membranes: a solution for highly efficient CO2 capture?
%D 2015
* ROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND
%X The field of metal-organic framework based mixed matrix membranes (M(4)s) is critically reviewed, with special emphasis on their application in CO2 capture during energy generation. After introducing the most relevant parameters affecting membrane performance, we define targets in terms of selectivity and productivity based on existing literature on process design for pre- and post-combustion CO2 capture. Subsequently, the state of the art in M(4)s is reviewed against these targets. Because final application of these membranes will only be possible if thin separation layers can be produced, the latest advances in the manufacture of M-4 hollow fibers are discussed. Finally, the recent efforts in understanding the separation performance of these complex composite materials and future research directions are outlined.
%@ 1460-4744
%K hollow-fiber membranes
%K hansen solubility parameters
%K gas separation performance
%K carbn-dioxide capture
%K zeolitic imidazolate frameworks
%K nano-composite membranes
%K IGCC power-plants
%K of-the-art
%K nanocomposite membranes
%K hydrogen separation
doi 10.1039/c4cs00437j
%U http://hdl.handle.net/11556/180
%~ GOEDOC, SUB GOETTINGEN